Indian Minerals Yearbook  2017 on Antimony

This note condenses the key information on antimony from the Indian Minerals Yearbook  2017 (Part II: Metals & Alloys). It covers the metal’s natural occurrence, domestic resource status, principal uses, world‑wide reserves and production, trade flows, and future demand drivers. The aim is to give you a quick‑reference sheet for exams and rapid revision.

Antimony Resources Summary in India

  • Domestic reserves (as 1 Apr 2015)
    • Total estimated 10 588 t of antimony ore (≈ 174 t of metal) – all inferred.
    • Located in Lahaul & Spiti (Himachal Pradesh); minor occurrences reported in AP, J&K, Jharkhand, Karnataka, Uttarakhand.
  • Primary orestibnite (Sb₂S₃, 71.4 % Sb). Other ores: jamesonite (Pb2Sb2S5) and senarmontite/valentinite (Sb2O3).
  • Geochemical classchalcophile: associates with sulfur and heavy metals (Pb, Cu, Ag).

Applications for Antimony

ApplicationTypical Antimony FormKey Role
Flame‑retardantsAntimony trioxide (Sb₂O₃)Synergist with Br/Cl; ~55 % of global antimony demand
Lead‑acid batteriesAntimony alloyed with leadIncreases hardness & cycle life
Electronics & opticsAntimony sulfide (Sb₂S₃)Infra‑red detector, diodes, acoustic devices
Safety matchesAntimony sulfideFuel component
Glass & ceramicsAntimony compoundsDecolourising & refining
Pharmaceuticals & cosmeticsVarious Sb‑compoundsSpecialized therapeutic agents
Practical insight: Antimony’s expansion on cooling is unusual; designers must accommodate dimensional change in alloy components.

Substitutes & Recycling

  • Battery hardeners – tin, calcium, copper, selenium, cadmium, strontium, sulfur; low‑maintenance batteries now favour calcium.
  • Flame‑retardant alternatives – organic inhibitors, hydrated aluminium oxide.
  • Rubber & polymer substitutes – tellurium, selenium.
  • Paint & pigment replacements – titanium, zinc, chromium, tin, zirconium compounds.
  • Recycling – secondary antimony is mainly recovered as antimonial lead at lead‑smelters (largely re‑used in lead‑acid batteries).

World Reserves & Production

Global reserves (metal content)1.5 million t; dominant countries:

CountryReserve (t)Share
China480 00032 %
Russia350 00023 %
Bolivia310 00021 %
Australia140 0009 %
Turkey100 0007 %
Others≤ 60 000 each

2020 production capacity is predicted at around  143 000 t metal (down 1 % YoY). It is predicted that China will overtake around 75% of global supply output. In other regions, Tajikistan (8 %), Russia (5 %), and Australia (3 %).

India Exports & Imports of Antimony in 2016 – 2017

Exports from India

  • Antimony ores & concentrates: 46 t (down from 264 t). Main destinations: USA (62 %), Pakistan (24 %).
  • Antimony alloys & scrap: 1 668 t (down ~ 18 %).
  • Unwrought powders: 1 667 t.
  • Antimonial lead: 12 231 t (≈ 2‑fold increase).

Imports to India

  • Ores & concentrates: 4 756 t (↓ 11 %). Suppliers: Tajikistan (55 %), Kazakhstan (34 %), Russia (6 %).
  • Alloys & scrap: 864 t (↓ 25 %); mainly from China (83 %).
  • Unwrought powders: 842 t.

Technical Possibilities & Recycling (Brief)

  • Stabilisers for specialised plastics.
  • High‑antimonial lead batteries for electric vehicles (deep‑cycle advantage).
  • Semiconductor devices: night‑vision, space‑based astronomy, DVD manufacture.

Future Outlook

  • Flame‑retardant sector drives ≈ 55 % of primary antimony demand; antimony trioxide accounts for ~ 90 % of global consumption.
  • PET catalysts: antimony‑based catalysts dominate (~ 90 % usage).
  • Emerging tech – Germanium‑antimony‑telluride Phase‑Change RAM (PRAM) chips, targeting mobile and camera markets.
  • Battery market: recent lead‑acid innovations may reduce antimony use, offsetting growth elsewhere.
  • Supply outlook – world reserves are ample; USGS projects modest consumption rise, especially from flame‑retardants, lead‑acid batteries, and Asian plastics.

Key Take‑aways

  • India holds only inferred antimony resources (≈ 174 t metal) in Himachal Pradesh; no domestic production – all demand is met by imports.
  • Flame‑retardants dominate global consumption; keep this sector in mind for demand‑side questions.
  • China remains the strategic hub for both reserves and output; any geopolitics‑related scenario will likely centre on Chinese policy.
  • Substitutes (calcium, organic retardants) are gaining market share – useful when evaluating sustainability or cost‑benefit analyses.

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